Activation of ammonia and hydrazine by electron rich Fe(ii) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(iii) amido intermediate
نویسندگان
چکیده
منابع مشابه
Facile hydrogen atom transfer to iron(iii) imido radical complexes supported by a dianionic pentadentate ligand
University of Calgary, Department of Chemi Alberta, Canada, T2N 1N4. E-mail: wpiers@ Department of Chemistry, University of Roc LPCNO, Université de Toulouse, INSA, UPS, Toulouse, France † Electronic supplementary informa characterization data, experimental and c data for [B2Pz4LiPyH]2, 1$THF, 1, 2$A 1439242–1439246. For ESI and crystallog format see DOI: 10.1039/c6sc01433j Cite this: Chem. Sci...
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15 صفحه اولCatalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalys...
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a comparative move analysis of the introduction sections of ma theses by iranian and native post-graduate students
since esp received universal attention to smooth the path for academic studies and productions, a great deal of research and studies have been directed towards this area. swales’ (1990) model of ra introduction move analysis has served a pioneering role of guiding many relevant studies and has proven to be productive in terms of helpful guidelines that are the outcome of voluminous productions ...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2021
ISSN: 2041-6520,2041-6539
DOI: 10.1039/d0sc06466a